* Vanadium
  Z = 23  Z_val = 5

* Units: Hartrees

* Type : DF AREP GAMESS parameterization

* Core radii

  l value                 core radii (au)
  -------                 ---------------
     s                         2.72   
     p                         2.62   
     d                         0.82   

* Localisation radii, (r_loc, |V_l - V_l'|<10^-5 for r>r_loc and all l,l')

  Pseudopotential Type       r_loc (au)
  --------------------      -----------
  Localised (Grid)             3.19   
  Parameterised (Gaussians)    4.70   


* Eigenvalues of the 3d(3)4s(2) state

                LS Coupling [4F]             jj Coupling [AV] 
  l value    All-el HF    Pseudo HF       All-el DF    Pseudo HF
  -------    ---------    ---------       ---------    ---------
     s       -0.23058     -0.23277        -0.23463     -0.23456
     d       -0.50962     -0.49639        -0.44988     -0.44947

  (All-electron DF eigenvalues are averaged over spin)


* Energy terms of the Pseudo HF (LS) 3d(3)4s(2) [4F] state

  kinetic energy            =            13.97809
  el-ion interaction energy =           -24.06495
                    (s part =           -3.02278)
                    (d part =           -21.04217)
  Hartree energy            =            5.32463
  exchange energy           =           -1.25856
  -------------------------------------------------
  total energy              =           -6.02078


* Excitation Energies

  Configuration             LS Coupling                    jj Coupling    
                        All-el HF     Pseudo HF        All-el DF     Pseudo HF
                   Term  Energy        Energy     Term  Energy        Energy
                   ----  ------        ------     ----  ------        ------
  3d(3)4s(2)        4F   0.00000       0.00000     AV   0.00000       0.00000
  3d(4)4s(1)        6D   0.01069       0.01685     AV   0.05211       0.06140
  3d(4)4p(1)        6F   0.21736       0.22511     AV  -0.12004      -0.11418

  The All-el HF results have been corrected for relativistic effects
  by including mass-velocity, Darwin, and spin-spin contact terms.